Methanediide Formation via Hydrogen Elimination in Magnesium versus Aluminium Hydride Complexes of a Sterically Demanding Bis(iminophosphoranyl)methanediide
نویسندگان
چکیده
منابع مشابه
Methanediide Formation via Hydrogen Elimination in Magnesium versus Aluminium Hydride Complexes of a Sterically Demanding Bis(iminophosphoranyl)methanediide
Substituted bis(iminophosphoranyl)methanes are CH acidic compounds that can form complexes with formally dianionic central carbon centres. The reaction of H2C(Ph2P=NDip)2 (≡H2L), Dip = 2,6-diisopropylphenyl, with one equivalent of di-n-butylmagnesium afforded the methanide complex [HLMgnBu] 1. Treatment of Complex 1 with phenylsilane in aromatic solvents at elevated temperatures afforded the me...
متن کاملMethanediide Formation via Hydrogen Elimination
Substituted bis(iminophosphoranyl)methanes are CH acidic compounds that can form 15 complexes with formally dianionic central carbon centres. The reaction of H2C(Ph2P=NDip)2 (≡ 16 H2L), Dip = 2,6-diisopropylphenyl, with one equivalent of di-n-butylmagnesium afforded the 17 methanide complex [HLMgnBu] 1. Treatment of complex 1 with phenylsilane in aromatic solvents 18 at elevated temperatures af...
متن کاملSynthesis and characterisation of magnesium complexes containing sterically demanding N,N'-bis(aryl)amidinate ligands.
Condensation reactions of carboxylic acids and anilines in the presence of polyphosphoric acid trimethylsilyl ester (PPSE) afforded a range of sterically demanding N,N'-bis(aryl)amidines, RN{C(R')}N(H)R [R = Mes (Mes = 2,4,6-trimethylphenyl), R' = Cy (Cy = cyclohexyl) L¹H; R = Dipp (Dipp = 2,6-diisopropylphenyl), R' = Cy L²H; R = Mes, R' = Ph L³H; R = Dipp, R' = Ph L⁴H; R = Mes, R' = Dmp (Dmp =...
متن کاملMagnesium, zinc, aluminium and gallium hydride complexes of the transition metals† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6cc05702k
The preparation and applications of heterobimetallic complexes continue to occupy researchers in the fields of organometallic, main group, and coordination chemistry. This interest stems from the promise these complexes hold as precursors to materials, reagents in synthesis and as new catalysis. Here we survey and organise the state-of-the-art understanding of the TM-H-M linkage (M = Mg, Zn, Al...
متن کاملPitting-induced hydrogen embrittlement of magnesium- aluminium alloy
In this study, the pitting corrosion susceptibility and its role on the hydrogen embrittlement behavior of AZ80 magnesium alloy were studied using slow strain rate testing (SSRT), electrochemical technique and immersion test method. The electrochemical and immersion tests in chloride-containing solution revealed severe pitting corrosion in the alloy. The SSRT results of the alloy under continuo...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Inorganics
سال: 2017
ISSN: 2304-6740
DOI: 10.3390/inorganics5020029